add a divider to your dropdown nav toggles

HTML

<!-- Example single danger button -->
<div class="btn-group">
  <button type="button" class="btn btn-danger dropdown-toggle" data-bs-toggle="dropdown" aria-expanded="false">
    Action
  </button>
  <ul class="dropdown-menu">
    <li><a class="dropdown-item" href="#">Action</a></li>
    <li><a class="dropdown-item" href="#">Another action</a></li>
    <li><a class="dropdown-item" href="#">Something else here</a></li>
    <li><hr class="dropdown-divider"></li>
    <li><a class="dropdown-item" href="#">Separated link</a></li>
  </ul>
</div>

Scripts

<link href="https://cdn.jsdelivr.net/npm/bootstrap-dark-5@1.1.3/dist/css/bootstrap-nightshade.min.css" rel="stylesheet">
<script src="https://cdn.jsdelivr.net/npm/@popperjs/core@2.9.2/dist/umd/popper.min.js" integrity="sha384-IQsoLXl5PILFhosVNubq5LC7Qb9DXgDA9i+tQ8Zj3iwWAwPtgFTxbJ8NT4GN1R8p" crossorigin="anonymous"></script>
<script src="https://cdn.jsdelivr.net/npm/bootstrap@5.0.2/dist/js/bootstrap.min.js" integrity="sha384-cVKIPhGWiC2Al4u+LWgxfKTRIcfu0JTxR+EQDz/bgldoEyl4H0zUF0QKbrJ0EcQF" crossorigin="anonymous"></script>